
How do we find the SALCs? - Chemistry Stack Exchange
Sep 10, 2021 · Suddenly, she specifies the actual SALC, but I don't understand how she gets there, and the SALC that are depicted seem to be completely random, they do not make any sense to my eye. …
Methane T2 SALCs - Chemistry Stack Exchange
Feb 5, 2019 · If I perform any number of Schmidt orthoganalizations using the other 3 rows of the projection operator table, I always end up with an exceedingly strange SALC, regardless of …
transition metals - Symmetry and SALC: choosing coordinate basis ...
Feb 2, 2017 · Symmetry and SALC: choosing coordinate basis Ask Question Asked 9 years ago Modified 8 years, 7 months ago
How is the SALC of Dz2 orbital used to construct its LGO in an ...
Feb 13, 2025 · How is the SALC of Dz2 orbital used to construct its LGO in an octahedral ligand field? Ask Question Asked 11 months ago Modified 11 months ago
Do SALC-AOs really belong to their symmetry species?
Apr 25, 2020 · The A 1 SALC-AO is identical under each operation, so it makes sense that it would belong to A 1. But if I want to confirm that the two E SALC-AOs belong to E, how would I do that?
MO diagram of BeH₂ - Chemistry Stack Exchange
Apr 17, 2019 · I was learning about the MO diagrams of triatomic molecules and was left slightly confused about $\\ce{BeH2}$. A picture of the MO is shown below: When looking at the …
Mulliken Labels: How do I tell apart E, doubly degenerate, symmetry ...
Nov 7, 2023 · In other words, the $\mathrm {e_g}$ SALC overlaps with the $\mathrm {e_g}$ set of d-orbitals, so all is well and good. I'm aware I'm not answering why the SALCs lack a third member. …
Orbital mixing in square planar D4h complexes
Nov 15, 2016 · 1 Answer All orbitals of the same symmetry will interact (mix) to some degree. So the ligand SALC will interact with both $\mathrm {a_ {1g}}$ orbitals on the metal. The degree of …
Help determining normalisation constant in SALC of methane
Nov 16, 2020 · We have been told that a symmetry adapted combination of four hydrogen orbitals is used to create localised hydrogen orbitals for methane. These orthonormal combinations are …
molecular orbital theory - C5v E1 SALC production using Full Projection ...
Feb 11, 2019 · I have another SALC question. @Andrew and @user5713492 did a phenomenal job clarifying my previous confusion with Methane T2 SALC production, so I attempted to apply this to a …